Radical Bridged Ln 4 Metallocene Complexes with Strong Magnetic Coupling and Large Coercive Field
نویسندگان
چکیده
Die Verstärkung der magnetischen Kopplung in 4f-basierten Einzelmolekülmagneten ist eine Herausforderung. In ihrem Forschungsartikel auf S. 24408 setzen Akseli Mansikkamäki, Muralee Murugesu und Mitarbeiter stark delokalisierte Tetrazinyl-Radikale zur Verbrückung von 4f-Metallocenen ein, um vierkernige Komplexe zu bilden. Eine gründliche Untersuchung Eigenschaften theoretische Studien stützen ein radikalinduziertes “Giant-Spin”-Modell mit starken Austauschwechselwirkungen, SMM-Verhalten bei Nullfeld einem Koerzitivfeld 3 T.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202111796